Changhong Ke, PhD, Binghamton University
Our research progress from this PRF support also includes the
mechanical testing of carbon nanotubes and the interfacial binding interaction
among tubes in the bundle structure and between nanotube and substrate. Our research results reveal that the
interfacial interaction between nanotubes can have a significant impact on its
mechanical deformation, including the adhesion-driven buckling. Our research
also reveals that the interfacial interaction between the CNT and the substrate
is strongly modulated by the deformation of the CNT. These results, which were reported
in two peer-reviewed journal articles, are very useful to the understanding of the
interfacial binding interaction in 1D nanostructures and the pursuit of
adhesion-involved applications, including polymer composites.
In addition to the study of the interfacial stress transfer
between PMMA and CNT, we are pursuing new research direction to study the
interfacial stress transfer between polymer and graphene sheet, which is a key
and challenging issue for the emerging graphene-based polymer composite. This
new research direction is a direct extension of the research work supported by
this PRF grant. The manufacturing
process that we demonstrated for engineering free-standing CNT bridges is
currently being applied to fabricate free-standing graphene sheet with one end
embedded into the polymer. The interfacial shear strength between the graphene
and the polymer will be characterized by in-situ SEM nanomechanical testing
which utilizes a flexible AFM cantilever as force sensor. Our experimental measurements will be
interpreted by molecular dynamical simulation through an established
collaboration with Dr. Rajesh Khare at
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