Reports: UR351716-UR3: Ligands for the Cobalt-Catalyzed Dimerization of Alpha Olefins
Richard D. Broene, Bowdoin College
Tethered Ligands
Building upon our successful synthesis of a Cp*quinolineCoI2
last year, we attempted to reduce the Co(III) to Co(I) in the presence of
ethene to form our pre-catalyst.
Scheme 1.
Isocyanides.
We synthesized and purified six para-substituted
phenylisocyanides that span the electronic range from -NO2 to -OMe.
Scheme 2.
Planar Ligands.