John K. Grey, University of New Mexico
This research used new resonance Raman spectroscopic imaging techniques to quantify and spatially map current-carrying and trapping sites in promising polymer composite solar cells. We chose polythiophene systems that exhibit remarkable ordering characteristics (i.e. aggregation) that are doped with fullerene derivatives to facilitate charge generation in solar cell devices. These composites are among the most promising systems for efficient light energy conversion although a number of fundamental issues are still unresolved related to their performance. For example, very little is understood about the role of local polymer chain packing and aggregation characteristics that can drastically alter charge transport properties.
We
next pursued combining our chemical imaging with approach to perform combined electrical
imaging studies in a functioning device structure. A major advantage of our approach over existing
scanned-probe techniques is that polymer properties can be studied in realistic
devices in a completely non-invasive fashion. In this experiment, the laser light was modulated using
either optical choppers or acoustic-optical modulators and focused to a
diffraction-limited spot inside a functioning P3HT/PCBM solar cell device. By using resonance excitation, the
photovoltaic cycle was initiated allowing for measurement of local
photocurrents using lock-in techniques while simultaneously measuring Raman
spectra. Fig. 2 shows a simple
schematic of the experiment along with representative Raman and photocurrent
images generated from a P3HT/PCBM solar cell device. This work demonstrated that highly aggregated polymer
regions actually contribute less to photocurrent generation
which shows that no fullerenes can fit between the highly ordered
polymer chains. An The
new insights afforded from these experiments were instrumental for the PI's recently successful NSF CAREER proposal
application. This research
also involved undergraduates (including two female students) who have appeared
on our publications.
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