Timothy E. Long, Virginia Polytechnic Institute and State University
Complementary
multiple hydrogen bonding polymers offer potentially superior mechanical integrity
compared to conventional hydrogen bonding polymer systems. Moreover, CMHB units provide an
efficient molecular recognition and self-assembly process due to the high
hydrogen bonding association constant. Nucleobase-containing linear and branched copolymers
exhibited DNA-like melting behavior and a stronger temperature dependence of
melt viscosity compared to non-hydrogen-bond containing polymers, suggesting
possible advantages as thermo-responsive polymers to self-heal at relatively
low temperatures. Utilizing
CMHB units in the design of a self-healing polymer that is both reusable and
durable may facilitate recycling of hard-to-dispose plastics for environmental
security and energy saving. Our studies start with determining the
reactivity ratios of styrenic adenine monomer (VBA) and tert-butyl acrylate (tBA)
utilizing our newest instrument, a Mettler-Toledo ReactIR 45M, which allows us
to monitor in situ the infrared
spectrum of the reaction contents and ultimately the reaction kinetics. (Figure 1) According to the Mayo-Lewis
equation, the reactivity ratios for styrenic adenine and tBA were determined to be 0.41±0.02 and 0.42±0.02, respectively.
The literature reactivity ratios for styrene and tBA were 0.89 and 0.29, respectively, in toluene. The difference in
the reactivity ratios resulted from the change of solvent, which led to a
higher Collaborations with Eastman Chemical and KratonTM
Polymers revealed the suitability of this novel functional hydrocarbon platform
for both adhesive and elastomer technologies, respectively. Studies showed that CMHB greatly influenced
corresponding polymer physical properties, such as mechanical and morphological
behavior. Our attention on tailored, self-assembled nucleobase-containing
polymers as membranes provides structure and ionic transport relationships that
suggest block copolymer structures for desalination and ion-transport. Current efforts are focused on
the preparation of adenine and thymine based on acrylate functionality. The
monomers will be used to demonstrate the role of sequenced hydrogen bonding on
morphological and rheological performance.
Moreover, our efforts will continue to address the new area of
"supramolecular click" chemistry wherein the functional group is located on the
polymer template using molecular recognition. An important question arises
concerning the selective nature of the functionalization, and the ability for a
molecular guest to selectively locate the complementary pair in the presence of
other nucleobases is an important aspect of continued research efforts. ADDIN
EN.REFLIST
Copyright © American Chemical Society