The Houdry Process

The Houndry Process
As an avid participant in the sport of automobile racing, Eugene Houdry was acutely aware of the importance of high-performance fuels for successful machine performance. As a Frenchman, Houdry was also aware of the growing need for gasoline in a country that was deficient in its own petroleum resources.

In 1922, Houdry learned about an exceptional gasoline derived from lignite that was being produced in a catalytic procedure by  E. A. Prudhomme, a pharmacist in Nice, France. Houdry visited Prudhomme and persuaded him to move to Beauchamp, near Paris, where Houdry and some of his business associates financed and set up a laboratory. For the next few years, Houdry worked closely with Prudhomme and others to develop a workable lignite-to-gasoline process.

Supported by the French government, Houdry's syndicate built a demonstration plant that processed 60 tons of lignite per day to produce oil and gasoline. The plant started operations in June 1929, but the results were disappointing and the process was not economically competitive. The government subsidy was withdrawn, and the plant was shut down in that same year.

During the lignite-to-gasoline process, the solid lignite was initially broken down by heat to produce viscous hydrocarbon oil and tarsthen the oil was further converted by an added catalyst to produce lower-boiling hydrocarbons similar to the gasoline fraction derived from petroleum. Although much emphasis had been placed by others on nickel-containing catalysts, Houdry discovered that a clay mineral named Fuller's Earth, a naturally occurring aluminosilicate, could convert the oil derived from lignite to a gasoline-like product. Working with this knowledge, Houdry focused his attention on the application of catalysis to petroleum processing.

In 1930, H. F. Sheets of the Vacuum Oil Company learned of Houdry's promising results using a catalyst to convert vaporized petroleum to gasoline, and invited him to come to the United States. After a successful trial run, Houdry moved his laboratory and associates from France to Paulsboro, New Jersey.

The Houdry Process Corporation was founded in 1931, a joint venture of Houdry with his associates at the Vacuum Oil Company. That same year, Vacuum Oil merged with Standard Oil of New York to form the Socony-Vacuum Oil Company (later Mobil Oil Corporation). In 1933, a 200-barrel-per-day Houdry unit was put in operation. But the Great Depression had weakened the oil business. Unable to finance Houdry's work any further, Socony-Vacuum gave him permission to seek support from other petroleum companies.

In late 1933, Houdry met with Sun Oil Company (later Sun Company) president J. Howard Pew and vice president for refining Arthur Pew, Jr. Shortly thereafter, Houdry, Socony-Vacuum, and Sun signed a joint development agreement. In the next few years, the Houdry process underwent further changes, including an innovative method for regenerating the catalyst after a short, ten-minute usage time.

Arthur Pew, Jr., in 1938.These results inspired Socony-Vacuum and Sun to proceed to commercialization. In April 1936, Socony-Vacuum converted an older thermal-cracking unit in Paulsboro into a semi-works unit using the Houdry process. In March 1937, Sun's new, fully commercial unit went into operation. Processing 15,000 barrels of petroleum per day, this unit featured such innovations as a molten-salt heat control technique and motor-operated valves controlled by timers. Almost 50 percent of the product was high-octane gasoline, compared with 25 percent from the more conventional thermal processes.

When Arthur Pew, Jr., presented the details of the successful commercial process at a 1938 meeting of the American Petroleum Institute, the industry was astounded. An article in Fortune magazine, entitled "Monsieur Houdry's Invention," said Pew "had dropped a bombshell." In 1940, the first large-scale plant for producing a synthetic silica-alumina catalyst began operations in Paulsboro.

 

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