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| Mysterious compound In 1961 Neil Bartlett was teaching chemistry at the University of British Columbia in Vancouver, Canada. Some years earlier, while experimenting with fluorine and platinum, he had accidentally produced a deep-red solid whose exact chemical composition remained a mystery. With the assistance of his graduate student Derek Lohmann, he vigorously pursued the identity of the red solid. After much research, they eventually found that the known gaseous fluoride, platinum hexafluoride (PtF6), was able to oxidize oxygen and produce the red solid, which he and Lohmann had identified as O2+PtF6-. What was most unusual about this compound was that it contained oxygen in the form of positively charged ions, although oxygen usually has a net negative charge. Oxygen normally pulls electrons from other atoms and is thus called an oxidizing agent or oxidant. But Bartlett believed that in this case, the PtF6 component was a more powerful oxidizing agent than even oxygen and was extracting electrons from oxygen, leaving oxygen with a net positive charge. Even though PtF6 was first prepared some years earlier by researchers at Argonne National Laboratory, its oxidizing power had not been recognized until Bartlett's research. It was this development that led Bartlett to theorize that if PtF6 could oxidize oxygen, then it might also be able to achieve the "impossible" task of oxidizing xenon, whose ionization potential (energy required to remove an electron) was very similar to that of oxygen.
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Forbidden union |
Mysterious compound |
Simple experiment Copyright
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